When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH3CHBrCH(CH3)O2_CrowleyMoortgat(1992)_298K_210-290nm(fit).txt |
NAME: | 2-bromo-1-methylpropylperoxy radical |
FORMULA: | CH3CHBrCH(CH3)O2 |
AUTHOR(YEAR): | CrowleyMoortgat(1992) |
T: | 298K |
λ: | 210-290nm(fit) |
BIBLIOGRAPHY: |
J.N. Crowley and G.K. Moortgat, "2-Bromoethylperoxy and 2-bromo-1-methylpropylperoxy radicals - Ultraviolet absorption spectra and self reaction rate constants at 298 K",
J. Chem. Soc. Faraday Trans. 88, 2437-2444 (1992);
DOI: 10.1039/FT9928802437
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COMMENTS: | Absorption cross sections measured using the molecular modulation technique; modulated production of the peroxy radical by the regularly interrupted photolysis of flowing Br2/C4H8/O2 mixtures; deuterium lamp as a light source, photomultiplier tube-monochromator arrangement at a single wavelength (resolution ca. 1.5 nm) or a diode-array camera (resolution better than 0.2 nm) Fitted results with deconvolution of HO2: σ(T) = σmax(T) exp{-a(T) [ln(λmax/λ)]2} with λmax = 247.4 nm, σmax = 4.31×10-18 cm2 molecule-1, and a = 56.7 |
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